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IATA Class 4 Flammable Solids

Class 4 dangerous goods are subdivided into one of three divisions:

  • Division 4.1 - Flammable Solids; Self-reactive Substances; Polymerizing Substances; and Desensitized Explosives
  • Division 4.2 - Substances Liable to Spontaneous Combustion
  • Division 4.3 - Substances Which, in Contact with Water, Emit Flammable Gases

Class 4 substances may present fire or explosion hazards due to the following risks:

  • May be ignited by heat, friction, sparks, or flames
  • May burn rapidly with flare burning effects
  • Powders, dusts, shavings, or cuttings may explode or burn with explosive violence
  • May reignite after fire is extinguished
  • May produce irritating, corrosive, and toxic gases
  • May ignite with contact with air or moisture

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